By far, the strongest greenhouse gas is water vapor, not because it is very strong of itself, but it absorbs nearly all outgoing energy in the infrared spectrum except in the so called atmospheric window, where it only partially absorbs. Yet water vapor is missing from the IPCC AR6 chart seen here:
IPCC has consistently treated the effect of greenhouse gasses as additive, but it is impossible to absorb more than 100% of all emitted energy for a given wavelength. This leads to an overestimation of absorption when 2 or more gasses are present. For example, if CO2 absorbs 90% of available energy at 13 μm and water vapor another 50%, the sum is 90% + (1 -0.9} * 0.5 = 95%, not 140%
This will change the relative importance of greenhouse gasses drastically so it must be tested against reality. We now have a good global satellite temperature record from 1980 to 2022 or 43 years:
During this time the temperature rise was 0.5 C, which translates to 2.375 W/m2 ERF
Water vapor.
This is a good chart to see the relative importance of all major greenhouse gasses:
It is to be noted that water vapor also absorbs the incoming solar radiation in certain wavelengths, but solar influx is assumed to be constant.
When average temperature rises 0.5 C, the possible absorption rises by 2.375 W/m2 minus the energy that escapes through the atmospheric window.Water vapor through saturation: is responsible for all of this increase except where other gasses also absorb in the atmospheric window, and in the atmospheric window the absorption must be proportionally shared, subject to the 100% absorption limitation.The atmospheric window is about 26% of all the emitted radiation so net water absorption is 0.74 * 2.375 = 1.6 W.m2 or 0.34 C. However, the relative humidity is also decreasing, see picture:
Between 1980 and 2022 the net humidity increase is 3.6% minus 0.75% relative humidity for a net increase of 3.54%. This increase only matters in the atmospheric window which is on average 25% saturated, so the total increase from water vapor increase is 0.26 * 2.375 * 0.25 * 0.9925 = 0.15 W/m2 or 0.03 C., to be added to the total before increase in humidity.This means that for a 0.5C temperature increase between 1980 and 2022 the total sensitivity to water vapor is 1.75 W/m2 or 0.37 C
Carbon dioxide
CO2 is the strongest greenhouse gas after water vapor. The only wavelength band that is meaningful is 13 to 17.4 μm and absorption occurs from both CO2 and water vapor. Since they exist together, the effect of each of them must be proportionally allocated, or the sum of them added would exceed 100%
Between 1980 and 2022 the CO2 levels rose from 335 ppm to 415 ppm or 24% increase. The temperature increase 0.5 C. The net temperature increase or ERF in the 13 to 17.4 μm band is 0.035C or +0.17 W/m2 for the water vapor and 0.04C or +0.19 W/m2 for the CO2. To see how the calculation was made, go to Appendix 1.
Methane.
Methane gas is created from a variety of sources, both man made and natural. See pie chart
The good thing about methane is that its lifetime in the atmosphere is only 10 to 15 years, and the real contribution to climate change is only 1/5th of what is commonly advertised, since iits absorption bands occur together with partly saturated absorption from water vapor. See appendix 2.
In 1980 the CH4 concentration was 1.6 ppm and will be 2.0 ppm in 2022 which results in an increase of the greenhouse effect of 0.035 C or 0.17 W/m2 ERF from rising levels of Methane since 1980.
N2O.
Atmospheric N2O levels averaged 336 ppb (parts per billion) during 2022, about and was 301 ppb in 1980. It is a 300 times stronger greenhouse gas than CO2 by itself, because its absorption is not saturated in the atmosphere. When water vapor is dominant it is diminished by over 70% since it is at the edges of the Atmospheric window. For calculations see Appendix 3.
In 1980 the N2O concentration was 0.3 ppm which results in an increase of the greenhouse effect of 0.0065 C or 0.031 W/m2 ERF from rising levels of N2O since 1980 .
Ozone.
Ozone occurs as stratospheric O3 which is good. It protects us from uv radiation. O3 in the troposphere is considered harmful if it is over 0.08% It is normally around 0,01% in the troposphere. For calculations and figures, see appendix 4.
When the earth’s temperature rises by 0.5C, from 1980 to 2022, the amount of tropospheric O3 probably rises by 2% (Lacking good data I am guessing wildly, in urban areas it may be much more, but this is global average). This comes to 0.0034C temperature increase or 0.016 W/m2 ERF from O3, from 1980 to 2022.
CFC gasses.
CFC’s are cheap and efficient gasses to use in refrigerators and air conditioners.Their use rose rapidly until it was discovered they destroyed the protective ozone layer in the stratosphere, so its use, got banned in 1994, later diminished including its use in inhalers. CFCs has since diminished slowly and is maybe already below the levels in 1980. See also Appendix 5.
HFC gasses.
HFCs replaced CFCs and are rapidly growing in use, and the compressor seals still leak. For pictures on why they are a growing concern for the future, see Appendix 6.
The temperature increase from 1980 to 2022 was 0.0015 C or 0.007 W/m2 ERF.
Summary of all greenhouse effect causes for temperature rise from 1980 until 2022:
Effect from water vapor increase: 0.37 C or 1.75 W/m2; 80.9% of total
Effect from rising CO2: 0.04C or 0.19 W/m2; 8.78% of total
Effect from rising Methane: 0.036 C or 0.17 W/m2, 7.86% of total
Effect from rising N2O: 0.0065 C or 0.031 W/m2 1.4% of total
Effect from rising Ozone: 0.0034C or 0.016 W/m2 0.7% of total
Effect from rising HFCs : 0.0015 C or 0.007 W/m2 0.3% of total
TOTAL TEMPERATURE CHANGE 1980 to 2022: 0.4544C or 2.164 W/m2
Conclusion
CO2 amounts to less than 10% if the temperature increase since 1980, and so does Methane. The green new deal is a pipe dream that does not solve the climate problem, but will make it worse.the price of lithium carbonate used in batteries has risen sixteen-fold between 2020 and late 2022. Since then, it has dropped to one third of its peak price. China has corned the market in Lithium for now. There is not enough Lithium to be economically and ecologically justifiable to mine to meet demand in the future. Since solar and wind power are intermittent supplier of electricity they can never be used as base supplier of energy. Other solutions must be offered
Actions to be taken
What congress is doing to solve the problem.
Congress has passed the anti-inflation bill that included over 300 billion to fight climate change, and it included more solar panels and wind turbine motors to be imported from China. The experience from Europe is that electricity from solar panels and windmills is 5.7 times as expensive as conventional power generation.
This analysis was done for 2019, before COVID. The situation is worse now, with electricity rares up to 80 c/kWh, topping $1 /kWh last winter in some countries before subsides.
Even at the current increased European Gas prices, the estimated excess expenditures on Weather-Dependent “Renewables” in Europe is still very large: $0.5 trillion in capital expenditures and $1.2 trillion excess expenditures in the long-term.
These simple calculations show that any claim that Wind and Solar power are now cost competitive with conventional fossil fuel (Gas-fired) generation are patently false. The figures give an outline of the financial achievements of Green activists in stopping fracking for gas in Europe, close on to $1.2 trillion of excess costs.
It would be better not to import any solar panels and wind power generators from China and let them pay for the extra cost rather than building more coal burning plants. After all they were planning to build over a thousand new plants between now and 2030, all legal under the Paris accord. This would benefit the world climate much more, since Chinese coal plants are far more polluting, since China has far less stringent environmental regulations than U.S.
U.S. uses 13.5% of the world’s coal, and eliminating U.S. CO2 emissions would in time reduce the world temperature by 0.023C, providing no other country, such as China and India would increase their use of Coal, which they are, to the total of 1300 new coal plants between now and 2030. This would raise global temperature by more than 0.06 C.
What congress should do instead.
a. What congress should do immediately.
- Immediately stop downblending U 233 and pass The Thorium Energy security act SB 4242a. See more here.
2. Remove Thorium from the list of nuclear source material. The half-life of Thorium232 is 14 billion years, so its radioactivity is barely above background noise. More importantly, while Thorium is fertile, it is not fissile and should therefore not be included in the list. This would make it far easier to mine rare earth metals, as long as the ore consists of less than 0.05% Uranium, but any amount of Thorium is allowed without classifying the ore “Source material”.
3. Separate nuclear power into 3 categories. a. conventional nuclear power. b. Thorium breeder reactors that make more U233 than it consumes, and c. Thorium reactors that reduce nuclear waste.
4. Stop buying solar panels from China. Stop buying wind turbine generators from China. Let them install those in China and pay 5 times as much for their electricity.
5. Immediately form a commission led by competent people, not politicians; to decide how to best expand the electric grid and to best harden it against electro-magnetic pulses, whether solar or nuclear and to safeguard it against sabotage.
6. Remove all subsidies on electric cars, solar panels and wind generators, but continue to encourage energy conservation.
7. Encourage research and development of Thorium fueled reactors, especially liquid salt reactors by drastically simplifying and speeding up the approval process. President Trump issued an executive order in the last month of his presidency EO 13972 specifying that the United States must sustain its ability to meet the energy requirements for its national defense and space exploration initiatives. The ability to use small modular reactors will help maintain and advance United States dominance and strategic leadership across the space and terrestrial domains. This EO should be expanded to include civilian small modular reactors, including Liquid salt Thorium reactors less than 200 MW, which are the only valid reactors for space exploration.
Appendix 1, CO2
The following chart shows both CO2 and H2O are absorbing greenhouse gases, with H20 being the stronger greenhouse gas, absorbing over a much wider spectrum, and they overlap for the most part. But it also matters in what frequency ranges they absorb.
For this we will have to look at the frequency ranges of the incoming solar radiation and the outgoing black body radiation of the earth. It is the latter that causes the greenhouse effect. Take a look at this chart:
The red area represents the observed amount of solar radiation that reaches the earth’s surface. the white area under the red line represents radiation absorbed in the atmosphere. Likewise, the blue area represents the outgoing black body radiation that is not absorbed. The remaining white area under the magenta, blue or black line represents the retained absorbed energy that causes the greenhouse effect.
Let us now take a look at the Carbon Dioxide bands of absorption, at 2.7, 4.3 and 15 μm. Of them the 2.7 and 4.3 μm bands absorb where there is little black body radiation, the only band that counts is at 14.9 μm, and that is in a band where the black body radiation is near its maximum. Let us first consider the CO2 alone in a dry atmosphere, that is one with no water vapor at all. We will investigate the concentration of 335 ppm (in 1980) and 415 ppm (in 2022)
The very top line of the top black band represents total absorption at 415 ppm, the bottom of the black black band represents absorption at 335 ppm. Divide the frequency spectrum in 3 parts, below 14 μm, 14-16 μm, and above 16 μm, In the 13 to 14 μm band 66% of available energy is absorbed at 335 ppm, 70% at 415 ppm. in the 14 to 16 μm band 100% of available energy is absorbed at both 335 and 415 ppm. In the > 16 μm the numbers are also 66 and 70%. In addition, temperature is 0.5 C higher at 415 than at 335 ppm, so available energy is 0.7 % higher at 415 ppm.
The net result is greenhouse gas contribution for CO2 is 5.10 C at 335 ppm and 5.26 C at 415 ppm and 1.5C higher ambient temperature for a dry atmosphere.
The normal way to account for greenhouse gasses contribution is to simply add together the CO2 contribution and the contribution from water vapor. This leads to the wrong result for in doing so, the total result is more than 100% for some energy band, because it is impossible to add more than 100% of all available energy for a given wavelength. Again, the spectrum of interest is 13 to 17.4 μm.
The first thing to notice is that no absorption exceeds 100% , so at 14.9 μm wavelength CO2 absorbed 100%, and water vapor absorbed another 75%, the total sum is still 100%. It is impossible to absorb more than 100% of the total energy available for that wavelength. Therefore between the wavelengths 14 and 16 μm all energy was absorbed regardless of CO2 concentration and water vapor concentration. The only fair way to allocate the absorption is proportionally, 57% to CO2 and 43% to water vapor. Likewise, the 13 to 14 μm band is not fully saturated, so the total absorption is 62% of available energy for CO2 and 33% for water vapor. In the 16 to 17.4 μm range the total absorption is 44% for CO2 and 55 % for water vapor. For CO2 at 335 ppm and average temp 13.5 C the total temperature rise, when proportionally allocated comes to 2.73 C for the CO2 and 2.30 C for the water vapor. For CO2 at 415 ppm and an average temp 0.5 C higher, at 14 C average the net temperature increase or ERF in the 13 to 17.4 μm band is 0.035C or +0.17 W/m2 for the water vapor and 0.04C or +0.19 W/m2 for the CO2.
Appendix 2, Methane
Atmospheric methane levels averaged 2.0 ppm (parts per million) during 2022, or around 25% greater than in 1980. It is a 28 times stronger greenhouse gas by itself unlike CO2, because its absorption is not saturated in the atmosphere. On the other hand the lifetime of Methane in the atmosphere is 10 to 15 years, some of the Methane eating bacteria will do its job. There is only one significant absorption band that absorbs in the atmospheric window at 7.7 μm, at the edge of the atmospheric window.
The picture shows a small peak at 7.7μm. This is because at lower wavelengths absorption from water vapor has nearly eliminated the CH4 contribution. Remember that total absorption can never exceed 100 %, so the maximum absorption from CH4 occurs at 7.7μm. At 1.6 ppm it amounts to a greenhouse effect of 0.68 C for a dry gas.
The only major absorption line at 7.7 μm has two side lobes, at 7.5 and 7.9 μm. In the 7.5 μm sideband water vapor already absorbs nearly all energy, so the NH4 is of little effect. In the 7.9 μm sideband water vapor is 50% saturated at that level and the NH4 net absorption is 20% the net greenhouse effect is one fifth of the effect for a dry gas, or 0.14 C. In 1980 the CH4 concentration was 1.6 ppm and will be 2.0 ppm in 2022 which results in an increase of the greenhouse effect of 0.035 C or 0.17 W/m2 ERF from rising levels of Methane since 1980
Appendix 3, N2O.
Atmospheric N2O levels averaged 336 ppb (parts per billion) during 2022, about and was 301 ppb in 1980. It is a 300 times stronger greenhouse gas than CO2 by itself, because its absorption is not saturated in the atmosphere. When water vapor is dominant it is diminished by over 70% since it is at the edges of the Atmospheric window. On the other hand the lifetime of N20 in the atmosphere is short and is typically greatest at 5 p.m. One of the major reasons for the N2O increase is the increase of fertilization with nitrates, the other is from diesel fumes from trains, boats, ships, trucks and mining equipment
The picture shows a double N2O peak at 7.4 and 7.8 μm. . At 0.336 ppm in 2022it amounts to a greenhouse effect of 0.325 C for a dry gas. In the 7.4 μm band water vapor is saturated, in the 7.8 μm band 80% is saturated by water vapor.In 1980 the N2O concentration was 0.3 ppm which results in an increase of the greenhouse effect of 0.0065 C or 0.031 W/m2 ERF from rising levels of N2O since 1980 .
N2O is commonly called laughing gas, and is hazardous in high concentrations, and should be limited in confined places, but in concentrations of under 1 ppm nobody laughs because of that.
Appendix 4, Ozone.
Ozone or 03 is good if it is in the stratosphere. There it helps to absorb the ultraviolet and cosmic rays from the sun and other cosmic radiation. Ozone is bad if it is near the ground. The total proportion of O3 in the troposphere is about 0.01 ppm, yet it is a substantial greenhouse gas because it forms by uv radiation in the stratosphere and mesosphere, and thus protecting us from uv damage. See figure:
The O3 in the troposphere on the other hand is bad. It is normally around 0.01 ppm, but is considered damaging if people are exposed to more than 0.08 ppm in an 8 hour period. This can happen in urban environments in warm and stagnant weather, typically through car traffic. It is a great greenhouse gas because its main absorption band is at 9.5 μm, right in the atmospheric window where the outgoing black body radiation is the greatest. See fig:
The dotted blue line at 9.5 μm represents the tropospheric absorption, the total absorption is between the brown and the solid blue line. The total greenhouse effect from O3 is 0.88C, but the stratosphere does not interact very much with the troposphere, so the stratospheric O3 does not count as a greenhouse gas, only tropospheric O3. The total contribution to the greenhouse effect from tropospheric O3 is about 1/5 of the total, because atmospheric O2 absorbs in the same band limits the temperature rise to 0.17C When the earth’s temperature rises by 0.5C, from 1980 to 2022, the amount of tropospheric O3 probably rises by 2% (Lacking good data I am guessing wildly, in urban areas it may be much more, but this is global average). This comes to 0.0035C temperature increase or 0.016 W/m2 ERF from O3, from 1980 to 2022.
Appendix 5, CFC gasses.
ChloroFluoroCarbon (CFC) gasses started to be manufactured at the beginning of the refrigeration age, replacing ice as the refrigerant. It soon appeared in the atmosphere, mostly due to leaks in the air conditioner compressor seals. It didn’t amount to much as a greenhouse gas even though it was five thousand times more efficient than CO2 as a greenhouse gas. It was discovered that CFCs ate up the Ozone in the stratosphere, and if it continued to increase it could deplete the protective Ozone layer faster than it could be produced. In fact it created an Ozone hole over Antarctica. So it got forbidden Jan 17, 1994, In 2020 even China stopped production. Since 1994 CFC are decreasing by about 1% per year, but cheating persisted, especially among poorer nations and China. By 2022 it will probably have a greenhouse effect of 0.01C or 0,05 W/m2 ERF.
Appendix 6, HFC gases.
CFC started to be phased out and replaced by HydroFluoroCarbons (HFC), less efficient and more expensive, but at least they do not deplete the Ozone layer that protects us from cancer. Some of the HFCs are even bigger greenhouse effect generators than CFC, but well worth it to protect the Ozone layer. Their biggest absorption bands are in the middle of the atmospheric window.
If nothing is done to control them they will increase from nothing in 1980 until 2022 and beyond. See fig: NOAA Research News
The temperature increase from 1980 to 2022 was 0.0014 C or 0.007 W/m2 ERF..
Len Bilén's blog, a blog about faith, politics and the environment. 